We discovered an issue: "undefined symbol: _ZN10QTextCodec11validCodecsEv" also documented on bitcointalk, https://bitcointalk.org/index.php?topic=655359.msg7498801#msg7498801 which meant bitcoin-qt could not be executed on CentOS (6.5).
We swapped to qt 4.8.6 when gitian building the release for linux, and it has fixed the issue, and has also improved the general rendering of the qt client.
Tested the result on various debian/ubuntu systems, and also centos 6.5, everything works as expected.
https://download.qt-project.org/archive/qt/4.8/4.8.6/ for source.
No code was updated other than references in the gitian descriptors for linux.