This is currently disabled, when it can likely be fixed and re-enabled: https://github.com/bitcoin/bitcoin/blob/673acab223c0f896767b1ae784659df9f95452ae/contrib/devtools/symbol-check.py#L210
A Guix build with the exception dropped shows there are symbols being exported in the RISC-V bins:
0/opt/homebrew/opt/binutils/bin/objdump -T bitcoind
1
20000000000080500 w DF .text 00000000000000a6 Base _ZNSt7__cxx1112basic_stringIcSt11char_traitsIcESaIcEEC1IS3_EEPKcRKS3_
3000000000007f6a0 w DF .text 0000000000000064 Base _ZNSt7__cxx1115basic_stringbufIcSt11char_traitsIcESaIcEED1Ev
4000000000007e9da w DF .text 0000000000000024 Base _ZNKSt5ctypeIcE8do_widenEc
5
6std::__cxx11::basic_string<char, std::char_traits<char>, std::allocator<char> >::basic_string<std::allocator<char> >(char const*, std::allocator<char> const&)
7std::__cxx11::basic_stringbuf<char, std::char_traits<char>, std::allocator<char> >::~basic_stringbuf()
8std::ctype<char>::do_widen(char) const